WPC ,U6x %no 0(ow"4 m 0J 0T0 0^ 0h 0rJ 0| 08 0 1uN 0d 0(' 0(OU*wU> AI o @  U0 o1 @4 < >%v~cv<\  `(Roman 10cpiX#|x<\  `(Roman 10cpiXx\  @ X@($DQUQD/;&xؖ U2 0Indent123  2" 0Indent20 23  2, 0Indent30 0 23  26 0Indent40 0 0 23  2@ 0Indent50 0 0 0 23  2J 0Indent60 0 0 0 0 23  2T 0Indent70 0 0 0 0 0 23  2^ 0Indent80 0 0 0 0 0 0 23    ?AGMSYaioIndent0I.A.1.a.(1)(a)i)a)P 8Mac DefaultMac Default ` X("$("$<  9p`(Roman<  9p`(&Times New Roman 1 2 3 4 5 C << GWPC',*#0C,*#0C  *  !5!.&(2 4,4UUEDQ?%?" !  )  ` C!#4$ ` \! `!C ` 'Q Page    www.mfri.org<  9p`(CharcoalWPC'w,0Q#ow,0Q#o  *  !5!.&(2 4,4UU- HQQ& !  '   ` V"Q InstructorGuideQ NotesC!'4$ ` \! `!C 4 !  '  PtPtHH(FG(HH(d'A  0Styl{WP}01  HH  2$HH  Geneva  <Px443!#4$*$$*$ KK  Geneva  Geneva .,6 Geneva   D2:De Geneva  D2:De Geneva ! .   $  X  X  ` X X ԛ  HazardousMaterialsOperationsX  InstructorGuide   SessionReference: 1 Topic: HazardousMaterialsOperationsRefresher99 LevelofInstruction: TimeRequired: ThreeHours Materials :0 0 4050Sandbags0 0 TwoSixFootLengthsTwoorFourInchPipe0 0 TwoCombustibleGasIndicators0 0 pHPaper0 0 SampleofCorrosiveandCombustibleLiquids References: 0 0 IFSTAHazardousMaterialsforFirstResponders(2ndEdition)0 0 HazardousMaterialsOperations,MFRI,January1996================================================================= PREPARATION : Motivation: Objective(SPO): 110 Thestudentwilldemonstratetheirknowledgeandunderstandingofbasicrequirementsforthehazardousmaterialsoperationsfirstresponderbysatisfactoryperformanceofpracticalactivities. Overview: 0 HazardousMaterialsOperationsRefresher0 0 0 Firstresponderroleandresponsibilities0 0 0 Defensivecontrolandcontainmentmeasures0 0 0 Basicmeteringandmonitoring0 0 0 Practicalactivitiesinvolvingmeteringandcontrol` X hX Session1@ HazardousMaterialsOperationsRefresher ̢SPO110 Thestudentwilldemonstratetheirknowledgeandunderstandingofbasicrequirementsforthehazardousmaterialsoperationsfirstresponderbysatisfactoryperformanceofpracticalactivities.EO1110 Demonstrateabasicknowledgeoftheroleandresponsibilitiesofafirstresponderatthehazardousmaterialsoperationslevel.#%%Xd#EO1120 Demonstrateabasicknowledgeofvariouscontrolandcontainmentmeasureswhichthehazardousmaterialsoperationsfirstrespondercanutilize.EO1130 Demonstrateabasicknowledgeoftheuseofselectedmeteringdevicesandtheuseoftheinformationobtained.EO1140 Demonstrate,throughpracticalactivities,basiccontainmenttechniquesandtheuseofmeteringdevices., W( ` X ,X I. RoleandResponsibilities(111)  A.0 TerminologyReview   1.0 Lowerexplosivelimit  2.0 Upperexplosivelimit  3.0 Specificgravity  4.0 Vapordensity  5.0 Ignitiontemperature  6.0 Flashpoint  7.0 pH(powerofhydrogen)  8.0 Effectsofheatonsubstances B.0 ProductIdentification  1.0 Shippingpapers  2.0 Placardsandlabels  3.0 Typeofcontainer  4.0 Occupancyandlocation C.0 ControlAccess  1.0 Identifyzones  2.0 Securearea  3.0 Denyaccess D. AssessRisk  1. Producthazard   a. Flammable   b. Toxic   c. Corrosive   d. Reactive0 &   2. Exposures   a. People   b. Property   c. Environment'    3. Factorscontributingtorisk   a. Weather   b. Terrain   c. Stateofproduct    1) Solid    2) Liquid    3) Gas(vapor)  4. Resourcesavailable   a.0 Firstresponsecapability   b.0 Specializedresources   c.0 Technicalassistance E. DefensiveControlMeasures  1.0 Avoidcontactwithproduct  2. Withintrainingandequipmentlevels II. DefensiveControlMeasures(112)  A.0 Dilution  1.0 Canproductbediluted  2.0 Willdilutionreducehazard  3.0 Doyouhaveadequateresourcestodilute&   B.0 VaporSuppression  1.0 Canvaporsbesuppressed  2.0 Howlongwillsuppressioncontrolhazard  3.0 Doyouhaveadequateresourcesforsuppression'  &   C. CoolContainer  1.0 Canitbedonesafely  2.0 Doyouhaveadequatewatersupplyforcooling  3.0 Willcontainercoolingcauseotherproblems'   D.0 Damming  1.0 Canitbedonesafely  2.0 Doyouhaveadequateresourcesfordamming  3.0 Basicdammingtechniques   a.0 Underflowdamforproductslighterthanwater   b.0 Overflowdamforproductsheavierthanwater E.0 Diking  1.0 Canitbedonesafely  2.0 Doyouhaveadequateresourcesfordiking  3.0 Involvesconstructingbarrieraroundopeningorarea F.0 Diverting  1.0 Canitbedonesafely  2.0 Doyouhaveadequateresourcesfordiverting  3.0 Involvesdirectlyflowelsewhere III. BasicMetering(113)  A.0 UseofMeters  1.0 Detectpresenceofsubstance  2.0 Providevaluerelativetosubstancepresent  3.0 Usedtodeterminezonesandassessriskandaction  &   B.0 TypesofMeters  1.0 Combustiblegasindicator    a.0 Measurespercentageoflowerexplosivelimit   b.0 Doesnotmeasureconcentrationofvapors   c. Onlymeasuresvapor   d.0 Alarmsat10%ofLEL   e.0 Mustmeteratalllevels   f.0 Reviewuseandoperation'    2.0 Oxygenmeter   a.0 Measurespercentageofoxygeninair   b.0 Alarmsat19.5%or23.5%  3.0 Carbonmonoxide   a.0 Measurespartspermillion   b.0 35ppmorlessacceptable   c.0 Tasteless,odorless,colorlessgas  4.0 pHpaper   a.0 Usetomeasurecorrosivelevelofliquid   b.0 Paperstripchangescolor;requireschartforinterpretation   c.0 7consideredneutral;07acids,714bases   d.0 Reviewuse C.0 InterpretationofData  1.0 PercentageofLELindicatespossibilityoffire   a.0 Ifmetergoesto100immediately,substanceisaboveLEL   b.0 Ifmeterisbelow100,issourcecontrolled   c.0 Hasareabeencheckedtoinsurethatvaporshavenotmoved   d.0 Isvaporheavierorlighterthanair&    2.0 pHlevelindicatespossibilityofcorrosive   a.0 Ifcorrosive,avoidcontact   b.0 Mayrequirecontainmenttocontrolfurtherdamage   c.0 Mayrequirematerialstoneutralizebytechnicians'  IV. PracticalActivities(114) NOTE: Divideclassintofourequalgroupsandassigneachtoonestation.Asworkiscompleted,studentwillrotatetosubsequentstations,untilcompletingallstations. A.0 ConstructingOverflowDam  1.0 Determinethatproducthasspecificgravityofmorethanone  2.0 Determinelocationofdam  3.0 Placedammingmaterial  4.0 Nodrainpiperequiredsincematerialwillsinkallowingwatertoflowoverdam B.0 ConstructingUnderflowDam  1.0 Determinethatproducthasspecificgravityoflessthanone  2.0 Determinelocationofdam  3.0 Placeinitialdamningmaterial  4.0 Insertdrainpipeandsecure  5.0 Placeremainingdammingmaterial&   C.0 DikingandDiverting  1.0 Determinelocationofdikebasedonterrainandflow  2.0 Determineplacementofdikingmaterial  3.0 Placedikingmaterial  4.0 Continuallyreassessdikeeffectiveness'  &   D.0 Metering  1. Turnonandcheckcalibrationofmeter  2.0 Placemeternearsampleandtakereading  3.0 Recordsamplenumberandmeterreading  4.0 Movetonextsampleandrepeat'   E.0 pHPaper  1.0 TearoffshortpieceofpHpaperandplaceintweezers  2.0 PlacepHpaperinsampleandtakereading  3.0 Checkcolorofpaperagainstchart  4.0 Recordsamplenumberandpaperreading  5.0 Movetonextsampleandrepeat NOTE: Eachstudentshouldsampleasleastoneproductwithmeterandphpaperandrecordreading,numberofsample,andname) ` X hX  SUMMARY:#` X hX#  Review: 0 HazardousMaterialsOperationsRefresher0 0 0 Firstresponderroleandresponsibilities0 0 0 Defensivecontrolandcontainmentmeasures0 0 0 Basicmeteringandmonitoring0 0 0 Practicalactivitiesinvolvingmeteringandcontrol̢ Remotivation:0 Stresstheimportanceofoperatingonlywiththelimitsofequipmentandtraining,andgenerallyinadefensivemode.Alsostresstheimportanceofpersonalsafetyandproperassessmentbeforetakingaction. Assignment: ================================================================= EVALUATION:̜